Make use of the simple NCBI ID converter API
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emanuil-tolev commented
http://www.ncbi.nlm.nih.gov/pmc/tools/id-converter-api/
Currently we're doing PMID -> DOI lookups by looking up the whole item like
xml_url = "http://eutils.ncbi.nlm.nih.gov/entrez/eutils/efetch.fcgi?db=pubmed&id=" + canonical_pmid[5:] + "&retmode=xml"