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You can go to
WooCommerce -> settings -> Tab Tax -> Standard rates
and import the CSV file (Spanish version): https://yourwebsite.com/wp-admin/admin.php?page=wc-settings&tab=tax§ion=standard -
Manage EU VAT in WooCommerce (and valid EU VAT Number) with the plugin EU/UK VAT Manager for WooCommerce
CarlosLongarela/WooCommerce-european-vat
WooCommerce european VAT taxex CSV to import and Spain special cases
GPL-3.0